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Team Equipo

 

ull

(click on photo for Research at NAMES- ULL video

Facultad de Física, Universidad de La Laguna, Tenerife, Canary Islands, Spain.

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Research Investigación

 magec(click photo for Intro Video for MAGEC Research Project

Up–conversion materials for enhancing photo–electrochemical processes.

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Collaborations Colaboraciones

colUniversity of Nottingham (UK), IGIC - Russian Academy of Sciences (Russia), Univeristy of Jena (Germany), Centre biomaGUNE (País Vasco, Spain)

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Imprimir

3D-printing and Up-conversion (J. Mater. Chem C, 2016)

Publication in J. Mater. Chem. C, 2016, 4, 801

 "Infrared-light induced curing of photosensitive resins through photon up-conversion for novel cost-effective luminescent 3D-printing technology"

 J. Méndez-Ramos; J.C. Ruiz-Morales; P. Acosta-Mora; N.M. Khaidukov.

UC
 
curing4
 
 
 
Here we explore the ground-breaking photonic approach for infrared-light induced photo-polymerization of organic resins by using photon up-conversion in rare-earth-doped luminescent materials. In particular, we show outstanding high-intense near-infrared to ultraviolet-blue up-conversion emissions from Tm3+-doped K2YbF5 crystals, energies of which perfectly match the activation energy of light-sensitive resins that contain photo-initiators for radical polymerisation, widely used in medical surgery, odontology or implants applications, as well as in microstereolithography three-dimensional (3D) printing technology. This innovative technique, in which a cost-effective and low-power continuous wave commercial near-infrared laser diode is used, establishes a significant step forward to the state-of-the-art, by offering lower nominal radiation power and exposure time requirements than those of simultaneous two-photon absorption techniques based on powerful femtosecond lasers. We also present quasi-instantaneous ‘‘laser-writing’’-like printing of 3D-structures, which exhibit visible luminescence under infrared light, for novel applications in 3D security-ink stamps or fluorescent labels for visual identification of orthodontic adhesives.
 
paper